Proton transfer reactions from H3+ ions to N2, O2, and CO molecules
β Scribed by J.K. Kim; L.P. Theard; W.T. Huntress Jr.
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 639 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0009-2614
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The gas phase ion/molecule reactions of the title ionic species with carbon suboxide have been studied by ion trap mass spectrometry and interpreted as the result of electrophilic addition of these ions on the electronrich central carbon of C 3 O 2 followed by CO loss.
## Abstract We report on the gas phase reactions of small Fe^+^~__n__~ clusters (__n__ = 2β10) with O~2~, N~2~O and CO~2~ in an FTβICR mass spectrometer. Under our experimental conditions, clusters of all sizes reacted readily with O~2~ and all but the dimer reacted with N~2~O. Only the smallest Fe
The rdt, cocii~c~cnts and product eon dlsrrlbutlons for rhc reactions ot OH\* and tlzO+ u ith N2\_ 02 h'0 X20 Xc, CO, CO? H2S Jnd 112 hd\c been dctermlned it 194 + 2 K usmg a selcctcd ton ilo\. rubc (SIFT) dppclrnrus These reactIons urre generally found to proLccd b\~ athcr proton or charge trsnsfcr