Ion/molecule reactions of C2H2N+, C2H4N+ and C3H4N+ ions from acetonitrile with neutral carbon suboxide
β Scribed by Olga Bortolini; Luciano Pandolfo; Carlo Tommaselli; Pietro Traldi
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 146 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0951-4198
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β¦ Synopsis
The gas phase ion/molecule reactions of the title ionic species with carbon suboxide have been studied by ion trap mass spectrometry and interpreted as the result of electrophilic addition of these ions on the electronrich central carbon of C 3 O 2 followed by CO loss.
π SIMILAR VOLUMES
Two new 1,2,3,5-dithiadiazoles, [4-(4Π-C 5 H 4 N)CN 2 S 2 ] (L 1 ) and [4-(3Π-C 5 H 4 N)CN 2 S 2 ] (L 2 ), with different pyridyl groups at the 4-position were prepared. As Lewis bases, the dithiadiazoles reacted with Lewis acids via their pyridyl groups to form acid-base adducts with retention of t
Ion/molecule reactions leading to formation of the diagnostically useful [C 3 H 4 N] ion (m/z 54), from acetonitrile CI plasma, have been studied using a tandem quadrupole mass spectrometer. Evidence is presented to demonstrate that [C 3 H 4 N] is produced from an ion/molecule reaction between [C 2