Proton magnetic resonance studies of cyclic compounds—VI: Cis- and trans-2,6-dimethylpiperidine and cis (2,4), cis (4,6), cis (2,6)-2,4,6-trimethylpiperidine
✍ Scribed by H. Booth; J.H. Little; J. Feeney
- Book ID
- 103399489
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 511 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4020
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THE DELICATE balance of the norcaradlene-cycloheptatriene equilibrium is of continuing concern to organic chemists.= One of the several factors which influence this equilibrium is the magnitude of the external angle at the 7 position of the cycloheptatriene ring. Our interest in this problem4'5 has
H NMR spectra of t-3-ethyl-r-2,~-6-diphenylpiperidine, t-3-ethyl-r-2,~-6-dipheny1-4-piperidone and several related compounds have been obtained in deuteriochloroform and deuteriotrifluoroacetic acid solutions, and compared with the spectra of their hydrochlorides in deuteriochloroform-hexadeuteriodi