Dehydrobromination of cis-2,6-Dibromo-4,4-dimethylcyclohexanone and of cis-2,6-Dibromo-4,4-diphenylcyclohexanone
โ Scribed by Bordwell, Frederick G.; Wellman, Keith M.
- Book ID
- 127062416
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 1022 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
The molecular skeleton of the title Schiff base compound, C 13 H 8 Br 2 INO, is essentially planar due to an intramolecular N-Hร ร รO hydrogen bond; the two aromatic rings make a dihedral angle of 4.4 (5) . The crystal packing exhibits short intermolecular Iร ร รBr contacts of 3.7226 (16) A ห.
The asymmetric unit of the title compound, C 10 H 9 Br 2 NO, consists of two molecules. In both molecules, the benzene and cyclopropyl rings are nearly perpendicular, with dihedral angles of 85.8 (4) and 75.5 (4) . In the crystal structure, there are no obviously short intermolecular contacts. Each