✦ LIBER ✦

Proton Affinity and Heat of Formation of Vinyloxy [CH2CHO]. and Acetonyl [CH2COCH3]. Radicals

✍ Scribed by Guy Bouchoux; Julia Chamot-Rooke; Danielle Leblanc; Philippe Mourgues; Michel Sablier

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 215 KB
Volume: 2
Category: Article
ISSN: 1439-4235
DOI: 10.1002/1439-7641(20010417)2:4<235::aid-cphc235>3.0.co;2-s

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetic studies of the reactions CH2I2 +

Kinetic studies of the reactions CH2I2 + HI⇄CH3I + I2 and 2 CH3I⇄CH4 + CH2I2 the heat of formation of the iodomethyl radical

✍ Shozo Furuyama; David M. Golden; Sidney W. Benson 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 489 KB 👁 1 views

The rate of the reaction CH212 + H I 2 CH,I + I , has been followed spectrophotometrically from 201 .O to 31 1 .Z0. The rate constant for the reaction I + CH,I, CH,I + I, fits the equation, log (k,/M-'sec-') = 11.45 f 0.18 -(15.11 f 0.44)/0. This value, combined with the assumption that E2 = 0 & 1 k

Excess molar volumes of [xCH3(CH2)4OH +

Excess molar volumes of [xCH3(CH2)4OH + (1 - x){CH3COCH(CH3)CH3 or CH3COCH2CH(CH3)CH3 or CH3CH(OH)CH(CH3)CH3 or CH3CH(CH3)OCOCH3 or CH3CH2CH(CH3)OCOCH3 or CH3(CH2)2CH(CH3)OCOCH3 or CH3CH(CH3)CH(CH3)CH3}] at temperatures from 288.15 K to 328.15 K and each at saturation pressure

✍ Pradeep Kumar; M.P. Bhaisare; A.P. Kudchadker 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 167 KB

Decomposition of methylamino and aminome

Decomposition of methylamino and aminomethyl radicals. The heats of formation of methyleneimine (CH2NH) and hydrazyl (N2H3) radical

✍ M. A. Grela; A. J. Colussi 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 314 KB

A kinetic analysis of the thermal decomposition of methylamino and aminomethyl radicals into methyleneimine, reactions (1) and ( ): (1) .0 ? 3 kcal/mol in excellent agreement with ion cyclotron resonance spectroscopy measurements and to a pi bond energy of E, = 55.0 kcal/mol in CH,=NH which is com

Pyrolysis of 2-phenylethylamines heats o

Pyrolysis of 2-phenylethylamines heats of formation of aminomethyl radicals R2NCH2 · (R = H, CH3)

✍ M. A. Grela; A. J. Colussi 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 410 KB

A kinetic study of the very low-pressure pyrolysis of ethylbenzene (I), 2-phenylethylamine (II), and N,N-dimethyl 2-phenylethylamine (111) (1) (2) (3) above 900 K yields the heats of formation of aminomethyl ( A ) and N,N-dimethylaminomethyl ( B ) radicals: AHf,300K(A) = 30.3 and AHf300K(B) = 27

Kinetics of gas-phase reactions of CH3OC

Kinetics of gas-phase reactions of CH3OCH2CF3, CH3OCH3, CH3OCH2CH3, CH3CH2OCH2CH3, and CHF2CF2OCH2CF3 with NO3 radicals at 298 K

✍ L. Chen; T. Uchimaru; S. Kutsuna; K. Tokuhashi; A. Sekiya; H. Okamoto 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 215 KB 👁 1 views

## Abstract Rate constants for the gas‐phase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d

Absolute rate constants for F + CH3CHO a

Absolute rate constants for F + CH3CHO and CH3CO + O2, relative rate study of CH3CO + NO, and the product distribution of the F + CH3CHO reaction

✍ Jens Sehested; Lene K. Christensen; Ole J. Nielsen; Timothy J. Wallington 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 204 KB 👁 2 views

Using a pulse-radiolysis transient UV-VIS absorption system, rate constants for the reactions of F atoms with CH 3 CHO (1) and CH 3 CO radicals with O 2 (2) and NO (3) at 295 K and 1000 mbar total pressure of SF 6 was determined to be By monitoring the for-Ϫ12 Ϫ11 3 Ϫ1 Ϫ1 (4.4 Ϯ 0.7) ϫ 10 , and k ϭ