Proton affinity and heat of formation of silylene
โ Scribed by Shin, Seung Koo; Beauchamp, J. L.
- Book ID
- 119996510
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 365 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The equilibrium for proton transfer involving acetone and ketene (CH$OCHsH++ CH2CO -CH$O++ CHsCOCH3) has been studied in a pulsed ion cyclotron resonance spectrometer. Vtiues of 193.6 r I and 194.1 c 1 kcal/mole (1 kcal/mole = 4.18 kjoules) are obtained for the proton affinities of acetone and keten
The static system decomposition kinetics of disilane (Si,H, A SiH, + SiH,, 538-587 K and 10-500 Torr), are reported. Reaction rate constants are weakly pressure dependent. and best fits of the data are realized with RHKM fall-off calculations using IogA,,. = 15.75 and E l , , = 52,200 cal. These par