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Determination of the proton affinity and absolute heat of formation of cyclopropenylidene

โœ Scribed by Leonard J. Chyall; Robert R. Squires


Book ID
103602688
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
967 KB
Volume
149-150
Category
Article
ISSN
0168-1176

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The proton affinity of ketene and the he
โœ P. Ausloos; S.G. Lias ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 361 KB

The equilibrium for proton transfer involving acetone and ketene (CH$OCHsH++ CH2CO -CH$O++ CHsCOCH3) has been studied in a pulsed ion cyclotron resonance spectrometer. Vtiues of 193.6 r I and 194.1 c 1 kcal/mole (1 kcal/mole = 4.18 kjoules) are obtained for the proton affinities of acetone and keten