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Protection and Polymerization of Functional Monomers. 27. Synthesis of Well-Defined Poly(4-vinyl-α-methylcinnamic Acid) by Means of Anionic Living Polymerization of 2-[1-Methyl-2-(4-ethenylphenyl)ethenyl]-4,4-dimethyl-2-oxazoline

✍ Scribed by Ishizone, Takashi; Tsuchiya, Junji; Hirao, Akira; Nakahama, Seiichi

Book ID: 121409368
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 172 KB
Volume: 31
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma980478b

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## Abstract Anionic polymerizations of __N__‐(4‐vinylbenzoyl)‐__N__′‐methylpiperazine (3a) and __N__‐(4‐vinylbenzoyl)morpholine (3b) were carried out in tetrahydrofuran at −78°C with oligo(α‐methylstyryl)‐dilithium, ‐disodium, and ‐dipotassium. The polymerizations of both 3a and 3b proceeded quanti