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Protection and polymerization of functional monomers. 21. Anionic living polymerization of (2,2-dimethyl-1,3-dioxolan-4-yl)methyl methacrylate

✍ Scribed by Mori, Hideharu; Hirao, Akira; Nakahama, Seiichi

Book ID: 120448166
Publisher: American Chemical Society
Year: 1994
Tongue: English
Weight: 633 KB
Volume: 27
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma00079a006

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## Abstract Anionic polymerizations of 2‐[(trimethylsilyl)oxy]ethyl methacrylate (1), 2‐[(__tert__‐butyldimethylsilyl)oxy]ethyl methacrylate (2), and 2‐[(methoxymethyl)oxy]ethyl methacrylate (3), the protected forms of 2‐hydroxyethyl methacrylate (HEMA), were carried out in THF at −78°C with 1,1‐di