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Protection and polymerization of functional monomers. 10. Synthesis of well-defined poly(4-vinylbenzaldehyde) by the anionic living polymerization of N-[(4-ethenylphenyl)methylene]cyclohexamine

✍ Scribed by Hirao, Akira; Nakahama, Seiichi


Book ID
126057350
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
666 KB
Volume
20
Category
Article
ISSN
0024-9297

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## Abstract Anionic polymerizations of __N__‐(4‐vinylbenzoyl)‐__N__′‐methylpiperazine (3a) and __N__‐(4‐vinylbenzoyl)morpholine (3b) were carried out in tetrahydrofuran at −78°C with oligo(α‐methylstyryl)‐dilithium, ‐disodium, and ‐dipotassium. The polymerizations of both 3a and 3b proceeded quanti

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## Abstract Anionic polymerization of 4‐(4′‐trimethylsilyl‐3′‐butynyl)styrene (2) was carried out in THF at −78°C for 0.5 h with oligo(α‐methylstyryl)lithium, ‐dilithium, and ‐dipotassium. Poly(2)s possessing predicted molecular weights and narrow molecular weight distributions (__M̄__~__w__~/__M̄_