✦ LIBER ✦

Products of the gas-phase photooxidation reactions of 1-propanol with OH radicals

✍ Scribed by K. Azad; J. M. Andino

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 133 KB
Volume: 31
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1999)31:11<810::aid-jck8>3.0.co;2-w

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✦ Synopsis

An experimental investigation of the hydroxyl radical initiated gas-phase photooxidation of 1-propanol in the presence of NO was carried out in a reaction chamber using gas chromatography mass spectrometry. The products identified in the OH radical reactions of 1-propanol were propionaldehyde and acetaldehyde, with corresponding formation yields of 0.719 Ϯ 0.058 and 0.184 Ϯ 0.030, respectively. Errors represent Ϯ2. The experimental product yields were compared to predictions made using chemical mechanisms.

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