Products from the gas-phase reaction of some unsaturated alcohols with nitrate radicals
✍ Scribed by Noda, J.; Hallquist, M.; Langer, S.; Ljungström, E.
- Book ID
- 120285066
- Publisher
- Royal Society of Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 204 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1463-9076
- DOI
- 10.1039/B000251H
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📜 SIMILAR VOLUMES
Rate coefficients for nitrate radical gas-phase reactions with prop-2-en-1-01 (allyl alcohol), but-I -en-3-ol, and 2-methylbut-3-en-2-01 have been determined. Both absolute (fast flow discharge with diode laser detection of NO,) and relative (batch reactor and FTIR spectroscopy) rate techniques were
## Abstract The bimolecular rate constant of __k__ (9.4 ± 2.4 × 10^−12^ cm^3^ molecule^−1^ s^−1^ was measured using the relative rate technique for the reaction of the nitrate radical (NO~3~•) with 4‐(2,6,6‐trimethyl‐1‐cyclohexen‐1‐yl)‐3‐buten‐2‐one (β‐ionone) at (297 ± 3) K and 1 atmosphere total