2-Butoxyethanol and benzyl alcohol reactions with the nitrate radical: Rate coefficients and gas-phase products
β Scribed by Joel C. Harrison; J. R. Wells
- Book ID
- 112136868
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 446 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0538-8066
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π SIMILAR VOLUMES
## Abstract The bimolecular rate constant of __k__ (9.4 Β± 2.4 Γ 10^β12^ cm^3^ molecule^β1^ s^β1^ was measured using the relative rate technique for the reaction of the nitrate radical (NO~3~β’) with 4β(2,6,6βtrimethylβ1βcyclohexenβ1βyl)β3βbutenβ2βone (Ξ²βionone) at (297 Β± 3) K and 1 atmosphere total
Rate coefficients have been determined for the reaction of butanal and 2-methylpropanal with NO 3 using relative and absolute methods. The relative measurements were accomplished by using a static reactor with long-path FTIR spectroscopy as the analytical tool. The absolute measurements were made us