Kinetics of the Gas-Phase Reaction of Some Unsaturated Alcohols with the Nitrate Radical
✍ Scribed by Noda, Jun; Nyman, Gunnar; Langer, Sarka
- Book ID
- 126481043
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 78 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
Rate coefficients for nitrate radical gas-phase reactions with prop-2-en-1-01 (allyl alcohol), but-I -en-3-ol, and 2-methylbut-3-en-2-01 have been determined. Both absolute (fast flow discharge with diode laser detection of NO,) and relative (batch reactor and FTIR spectroscopy) rate techniques were
## Abstract Rate coefficients for gas‐phase reaction between nitrate radicals and the __n__‐C~6~–C~10~ aldehydes have been determined by a relative rate technique. All experiments were carried out at 297 ± 2 K, 1020 ± 10 mbar and using synthetic air or nitrogen as the bath gas. The experiments were
## Abstract The gas‐phase reactions of the NO~3~ radical with 2‐methylthiophene, 3‐methylthiophene, and 2,5‐dimethylthiophene have been studied, using relative and absolute methods at 298 K. Determination of relative rate was performed using Teflon collapsible bag as the reaction chamber and gas ch