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Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR

✍ Scribed by M. Karl; H.-P. Dorn; F. Holland; R. Koppmann; D. Poppe; L. Rupp; A. Schaub; A. Wahner

Book ID: 106405397
Publisher: Springer Netherlands
Year: 2006
Tongue: English
Weight: 598 KB
Volume: 55
Category: Article
ISSN: 0167-7764
DOI: 10.1007/s10874-006-9034-x

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The gas-phase reaction of isoprene with the OH radical, in the presence of NO,, was investigated at 298 2 2 K and atmospheric pressure of air by long pathlength FT-IR spectroscopy. The primary products identified and their formation yields were: methacrolein, 0.22 2 0.05; methyl vinyl ketone, 0.29 2

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## Abstract A direct kinetics study of the product‐forming channels of the reaction of isoprene‐derived hydroxyalkylperoxy radicals with NO has been performed at 100 Torr pressure and 298 K using the turbulent flow technique with high‐pressure chemical ionization mass spectrometry for the detection

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Formation of 3-Methylfuran from the gas-

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3-Methylfuran has been identified as a product of the gas-phase reaction of the OH radical with isoprene, and under simulated atmospheric conditions a formation yield of 0.044 -t 0.006 was determined. In an analogous manner, the OH radical reaction with 1,3-butadiene formed furan with a yield of 0.0