Using relative rate methods, rate constants have been measured for the gas-phase reactions of 3-methylfuran with NO, radicals and 0, at 296 ? 2 K and atmospheric pressure of air. The rate constants determined were (1.31 ? 0.46) X lo-'' cm' molecule-' s-' for the NO, radical reaction and (2.05 ? 0.52
Measurements of the kinetics of the OH-initiated oxidation of isoprene: Radical propagation in the OH + isoprene + O2 + NO reaction system
โ Scribed by P. Stevens; D. L'Esperance; B. Chuong; G. Martin
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 147 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0538-8066
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โฆ Synopsis
ฯช12
ฯช1 ฯช1
9 ฯซ 10 mol s of 2) for the reaction of isoprene-based hydroxyalkyl peroxy radicals with NO.
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The kinetics of the gas-phase reactions of OH radicals, NO 3 radicals, and O 3 with indan, indene, fluorene, and 9,10-dihydroanthracene have been studied at 297 ฯฎ 2 K and atmospheric pressure of air. The rate constants, or upper limits thereof, for the O 3 reactions were (in cm 3 molecule ฯช1 s ฯช1 un
The products of the gas-phase reaction of the OH radical with 3-methyl-1-butene in the presence of NO have been investigated at room temperature and total pressure 740 torr of air by gas chromatography with flame ionization detection, in situ Fourier transform infrared absorption spectroscopy, and d