Using a relative kinetic technique, rate coefficients have been measured, at 296 ฯฎ 2 K and 740 Torr total pressure of synthetic air, for the gas-phase reaction of OH radicals with the dibasic esters dimethyl succinate The rate coefficients obtained were (in units of cm 3 molecule ฯช1 s ฯช1 ): dimethy
Product Study of the OH Radical and Cl Atom Initiated Oxidation of 1,3-Dioxane
โ Scribed by Dr. Jennie Moriarty; Dr. John C. Wenger; Prof. Howard W. Sidebottom
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 237 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1439-4235
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The Cl-and Br-initiated oxidations of CHCl"CCl 2 in 700 torr of air at 296 K have been studied using a Fourier transform infrared spectrometer. Rate constants k(Cl ฯฉ and were determined using a relative rate technique with ethane and ethylene as ฯช 1 ฯช 1 molecule s references, respectively. The majo
## Abstract Rate constants for several intermediate steps in the OHโinitiated oxidation of isoprene were determined using laserโphotolysis/laserโinduced fluorescence of OH radicals at total pressures between 3 and 4 Torr at 295 K. The rate constant for decomposition of the hydroxyalkoxy radical was
Reactions of CFSBr with H atoms and OH radicals have been studied a t room temperature a t 1-2 torr pressures in a discharge flow reactor coupled to an EPR spectrometer. The rate constant of the reaction H + CF3Br -CF3 + HBr (1) was found to be k l = (3.27 f 0.34) X cm:'/moleesec was determined for
Using a relative rate method, rate constants for the gas-phase reactions of 2methyl-3-buten-2-ol (MBO) with OH radicals, ozone, NO 3 radicals, and Cl atoms have been investigated using FTIR. The measured values for MBO at and total 298 ฯฎ 2 K 740 ฯฎ 5 torr pressure are: ฯช11 3 ฯช1 ฯช1 ฯช18 3 k ฯญ (3.9 ฯฎ 1.
## ฯช12 ฯช1 ฯช1 9 ฯซ 10 mol s of 2) for the reaction of isoprene-based hydroxyalkyl peroxy radicals with NO.