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Pressure-Induced Cis to Trans Isomerization of Poly(( p -nitrophenyl)acetylene) Prepared Using Rh Complex Catalysts. Extension of π Conjugation Length

✍ Scribed by D'Amato, Rosaria; Sone, Takeyuki; Tabata, Masayoshi; Sadahiro, Yoshikazu; Russo, Maria Vittoria; Furlani, Anita

Book ID
127192348
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
235 KB
Volume
31
Category
Article
ISSN
0024-9297

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Pressure-induced cis to trans isomerizat
Pressure-induced cis to trans isomerization of aromatic polyacetylenes prepared using a Rh complex catalyst: A control of π-conjugation length
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This study reports that stereospecific polymerization of aromatic acetylenes, e.g., p-methoxyphenylacetylene (pMOPA) and p-ethoxyphenylacetylene (pEOPA) was successfully performed to give polyacetylene selectively bearing cis-transoid forms in high yield when a Rh complex catalyst, [Rh(norbornadiene

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## Abstract **Summary:** A stereospecific polymerization of a novel aromatic acetylene containing an alkyl sulfide group, i.e., (__p__‐methylthiophenyl)acetylene (__p__MeSPA) was successfully performed to selectively give the corresponding polymer bearing a __cis__‐transoid structure as a main geom