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Pressure-Induced Cis to Trans Isomerization of Aromatic Polyacetylenes. 2. Poly(( o -ethoxyphenyl)acetylene) Stereoregularly Polymerized Using a Rh Complex Catalyst

✍ Scribed by Tabata, Masayoshi; Tanaka, Yoshiki; Sadahiro, Yoshikazu; Sone, Takeyuki; Yokota, Kazuaki; Miura, Ichiro

Book ID
126935873
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
265 KB
Volume
30
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES

Pressure-induced cis to trans isomerizat
Pressure-induced cis to trans isomerization of aromatic polyacetylenes prepared using a Rh complex catalyst: A control of Ο€-conjugation length
✍ Masayoshi Tabata; Takeyuki Sone; Yoshikazu Sadahiro; Kazuaki Yokota; Yuji Nozaki πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 158 KB πŸ‘ 1 views

This study reports that stereospecific polymerization of aromatic acetylenes, e.g., p-methoxyphenylacetylene (pMOPA) and p-ethoxyphenylacetylene (pEOPA) was successfully performed to give polyacetylene selectively bearing cis-transoid forms in high yield when a Rh complex catalyst, [Rh(norbornadiene

Pressure-Induced cis-to-trans Isomerizat
Pressure-Induced cis-to-trans Isomerization of Poly[(p-methylthiophenyl)acetylene] Prepared with a [Rh(norbornadiene)Cl]2 Catalyst – A Raman, UV-Vis, and ESR Study
✍ Kai Huang; Yasuteru Mawatari; Masayoshi Tabata; Takeyuki Sone; Atsushi Miyasaka; πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 162 KB

## Abstract **Summary:** A stereospecific polymerization of a novel aromatic acetylene containing an alkyl sulfide group, i.e., (__p__‐methylthiophenyl)acetylene (__p__MeSPA) was successfully performed to selectively give the corresponding polymer bearing a __cis__‐transoid structure as a main geom