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Pressure-Induced Cis to Trans Isomerization of Poly(o-methoxyphenylacetylene) Polymerized by Rh Complex Catalyst. A Raman, X-ray, and ESR Study

✍ Scribed by Tabata, M.; Takamura, H.; Yokota, K.; Nozaki, Y.; Hoshina, T.; Minakawa, H.; Kodaira, K.


Book ID
127089588
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
317 KB
Volume
27
Category
Article
ISSN
0024-9297

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Pressure-Induced cis-to-trans Isomerizat
✍ Kai Huang; Yasuteru Mawatari; Masayoshi Tabata; Takeyuki Sone; Atsushi Miyasaka; πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 162 KB

## Abstract **Summary:** A stereospecific polymerization of a novel aromatic acetylene containing an alkyl sulfide group, i.e., (__p__‐methylthiophenyl)acetylene (__p__MeSPA) was successfully performed to selectively give the corresponding polymer bearing a __cis__‐transoid structure as a main geom