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Preservation of chirality in the photochemical interconversion of trans-.DELTA.1,3-hexalin and trans,cis,trans-cyclodeca-1,3,5-triene

โœ Scribed by Matuszewski, Bogdan; Burgstahler, Albert W.; Givens, Richard S.


Book ID
126062697
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
387 KB
Volume
104
Category
Article
ISSN
0002-7863

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Intramolecular photocyclization of cis,
โœ Arnon Shani ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 131 KB

The transannular photocyclization of the cis,cis-cyclodecs-1,6+lienes to the tricyolo 5.3.0.02p6 --C 3 decane (1) may be explained due to the proximity in space of the two double bonds in the ~~hamnocks conformation I (2). Hence, in an intramolecular photocyclization of the isomeric trans,trans,cycl