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Photochemistry of cyclohepta-1,3-diene and cyclohepta-1,3,5-triene. Photochemical formation and chemical reactivity of the strained trans-isomer

โœ Scribed by Daino, Yoshihiko; Hagiwara, Shoji; Hakushi, Tadao; Inoue, Yoshihisa; Tai, Akira


Book ID
125811492
Publisher
Royal Society of Chemistry
Year
1989
Tongue
English
Weight
890 KB
Volume
3
Category
Article
ISSN
1472-779X

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Ab initio calculations on the one- and t
โœ V. Galasso ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 376 KB

The low-lying intmvalence and Rydberg excited states of cyclohepta-lJ,Striene and cycloocta-1,3,5,7-tetraene, accessed by one-and twc-photon absorption, have been investigated at ab initio level by utilizing RPA vertical transition energies and amplitudes. The nature of the first valence-like excite