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Cis-trans isomerization of 8-chlorohomotropylium salts and 7,8-dichlorocycloocta-1,3,5-triene

✍ Scribed by Rolf Huisgen; Johann Gasteiger

Publisher: Elsevier Science
Year: 1972
Tongue: French
Weight: 173 KB
Volume: 13
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)94129-2

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✦ Synopsis

The e-8-chlorohomotropylium tetrafluoroborate (;) (l), dissolved in liquid SOP, rearranges in a first-order reaction quantitatively to the exo-iao-

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