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Preparation, Structure, and Reactivities of Amido-Bridged Dinuclear Rhodium(III) and Rhodium(II) Complexes

โœ Scribed by Matsuzaka, Hiroyuki; Kamura, Teruo; Ariga, Ko; Watanabe, Yuko; Okubo, Takashi; Ishii, Tomohiko; Yamashita, Masahiro; Kondo, Mitsuru; Kitagawa, Susumu

Book ID
126235588
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
101 KB
Volume
19
Category
Article
ISSN
0276-7333

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Structural and Dynamic Studies on Amido-
Structural and Dynamic Studies on Amido-Bridged Rhodium and Iridium Complexes
โœ Cristina Tejel; Miguel A. Ciriano; Marta Bordonaba; Josรฉ A. Lรณpez; Fernando J. L ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 277 KB ๐Ÿ‘ 2 views

Treatment of [[M(mu-Cl)(diolefin)](2)] with the lithium salts of primary and secondary amines (LiNRR') in diethyl ether affords the complexes [[M(mu-NRR')(diolefin)](2)] (M=Rh, Ir; diolefin=1,5-cyclooctadiene (cod), tetrafluorobenzobarrelene (tfb); R'=H, R=tBu, Ph, 4-MeC(6)H(4); R=R'=Ph, 4-MeC(6)H(4