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Dinuclear Rhodium and Iridium Complexes with Mixed Amido/Methoxo and Amido/Hydroxo Bridges

✍ Scribed by Tejel, Cristina; Ciriano, Miguel A.; Bordonaba, Marta; López, José A.; Lahoz, Fernando J.; Oro, Luis A.

Book ID
126329883
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
113 KB
Volume
41
Category
Article
ISSN
0020-1669

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Structural and Dynamic Studies on Amido-Bridged Rhodium and Iridium Complexes
✍ Cristina Tejel; Miguel A. Ciriano; Marta Bordonaba; José A. López; Fernando J. L 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 277 KB 👁 2 views

Treatment of [[M(mu-Cl)(diolefin)](2)] with the lithium salts of primary and secondary amines (LiNRR') in diethyl ether affords the complexes [[M(mu-NRR')(diolefin)](2)] (M=Rh, Ir; diolefin=1,5-cyclooctadiene (cod), tetrafluorobenzobarrelene (tfb); R'=H, R=tBu, Ph, 4-MeC(6)H(4); R=R'=Ph, 4-MeC(6)H(4