Theoretical discussion of inorganic reaction mechanisms includes the role of the solvent, requiring estimates of thermodynamics of solvation in reactant, product or transition states. These are often made without reference to a "benchmark" calculation for a relatively simple, well-characterized syst
Preparation, spectroscopic assignments and relative stabilities of cis and trans species of o,o′-azodioxytoluene in the solid state and in solution
✍ Scribed by Michel Azoulay; Birgitta Stymne; Gunnar Wettermark
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 598 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
The relative configuration of the title compounds has been determined by 'H-NMR measurements at 300 MHz. In contradistinction to prevailing opinion, it was found that 4-OXO derivatives prefer the cis-configuration. While the cis/truns ratio is 82: 18 for the parent 1,2,3,4,4a,9,10, lOa-octahydrophen
Abwlute lifetimes of excited states cf D,O' and OD+ have been directly measured using the high frequency deflcction technique. Separate relative measurements show that the D23+ and OD+ lifetimes are 13-W ionger than those of H\*O+ and OH+ in the Sdme vibrational levels ' CHEMICAL PHYSICS LETTERS