Preparation of α-trialkylsilyl ketones from α-phenylseleno derivatives via their silyl enol ethers
✍ Scribed by Isao Kuwajima; Ryo Takeda
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 191 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Treatment of enol silyl ethers with the mild nitrating agent tetranitromethane gives good yields of unitroketones at room temperature and below.
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Abstmct: The reaction of 3,6-dimethary-3,6-dimethylcyclohea-l.4diene (I) with an ewess of dt@wtt silyl en01 ethers derived from ketones in the presence of zinc dichloride kads to the corresponding ketones regioselectively arylated at the (I position.