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Reactivity of 3,6-dimethoxy-3,6-dimethylcyclohexa-1,4-diene (Part 3). Regioselective α-arylation of ketones via their silyl enol ethers

✍ Scribed by Francisco Alonso; Miguel Yus

Publisher: Elsevier Science
Year: 1991
Tongue: French
Weight: 339 KB
Volume: 47
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)86514-5

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✦ Synopsis

Abstmct: The reaction of 3,6-dimethary-3,6-dimethylcyclohea-l.4diene (I) with an ewess of dt@wtt silyl en01 ethers derived from ketones in the presence of zinc dichloride kads to the corresponding ketones regioselectively arylated at the (I position.

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