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Preparation of new acetylide and vinylidene complexes of ruthenium

✍ Scribed by Gabriele Albertin; Stefano Antoniutti; Emilio Bordignon; Manuel Granzotto


Book ID
108354800
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
162 KB
Volume
585
Category
Article
ISSN
0022-328X

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Reactions of Ruthenium Vinylidene and Ac
✍ Chung-Yeh Wu; Hsien-Hsin Chou; Ying-Chih Lin; Yu Wang; Yi-Hung Liu πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 420 KB

## Abstract Solid‐state route to a cyclobutenone: Ruthenium perchlorocyclobutenonyl complex 2 is obtained by solid‐state photoisomerization of ruthenium trichloroacetyl acetylide complex 1. The four‐membered ring is sufficiently robust that transfer of the intact ligand could be readily achieved in