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Disubstituted vinylidene complexes of iron and ruthenium: nucleophilic properties of ν1-acetylide ligands

✍ Scribed by Steven Abbott; Stephen G. Davies; Peter Warner


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
218 KB
Volume
246
Category
Article
ISSN
0022-328X

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Reactions of Ruthenium Vinylidene and Ac
✍ Chung-Yeh Wu; Hsien-Hsin Chou; Ying-Chih Lin; Yu Wang; Yi-Hung Liu 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 420 KB

## Abstract Solid‐state route to a cyclobutenone: Ruthenium perchlorocyclobutenonyl complex 2 is obtained by solid‐state photoisomerization of ruthenium trichloroacetyl acetylide complex 1. The four‐membered ring is sufficiently robust that transfer of the intact ligand could be readily achieved in