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Some neutral ruthenium vinylidene complexes and a novel 1,3-elimination reaction: preparation of chiral ruthenium acetylides

โœ Scribed by Michael I Bruce; Ben C Hall; Natasha N Zaitseva; Brian W Skelton; Allan H White


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
513 KB
Volume
522
Category
Article
ISSN
0022-328X

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## Abstract Solidโ€state route to a cyclobutenone: Ruthenium perchlorocyclobutenonyl complex 2 is obtained by solidโ€state photoisomerization of ruthenium trichloroacetyl acetylide complex 1. The fourโ€membered ring is sufficiently robust that transfer of the intact ligand could be readily achieved in