Preparation of a novel cis isomer of bis(malonato)chromate(III) type complexes
✍ Scribed by Sumio Kaizaki; Naoko Hirota; Kayoko Segawa; Mieko Tanabe; Atsuko Okumura; Mika Yamamoto; J.Ivan Legg
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 445 KB
- Volume
- 191
- Category
- Article
- ISSN
- 0020-1693
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.012 A Ê Disorder in solvent or counterion R factor = 0.036 wR factor = 0.092 Data-to-parameter ratio = 24.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
## Abstract A new type of iridium(III) complex [__trans__‐Ir(ppy)~2~(PPh~3~)~2~]^+^ (1) has been prepared by a novel synthetic method and its structural and photoluminescent characteristics have been compared with those of the __cis__ analogue, [__cis__‐Ir(ppy)~2~(PPh~3~)(P(OPh)~3~)]^+^ (2) which h