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New Type of Photoluminescent Iridium Complex: Novel Synthetic Route for Cationic trans-Bis(2-phenylpyridinato)iridium(III) Complex

✍ Scribed by Chong Shik Chin; Min-Sik Eum; Song yi Kim; Choongil Kim; Sung Kwon Kang


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
118 KB
Volume
2006
Category
Article
ISSN
1434-1948

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✦ Synopsis


Abstract

A new type of iridium(III) complex [trans‐Ir(ppy)~2~(PPh~3~)~2~]^+^ (1) has been prepared by a novel synthetic method and its structural and photoluminescent characteristics have been compared with those of the cis analogue, [cis‐Ir(ppy)~2~(PPh~3~)(P(OPh)~3~)]^+^ (2) which has also been newly prepared in this study. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)