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Di-μ-α-pyrrolidinonato-bis­[cis-diammine­chloro­platinum(III)] sulfate dihydrate: a head-to-head isomer

✍ Scribed by Sakai, Ken ;Sakai, Itsuki ;Kajiwara, Takashi ;Ito, Tasuku


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
728 KB
Volume
60
Category
Article
ISSN
1600-5368

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A head-to-head isomer of di-μ-α-pyrrolid
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.012 A Ê Disorder in solvent or counterion R factor = 0.036 wR factor = 0.092 Data-to-parameter ratio = 24.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title compound, [Pt II 2 (C 4 H 6 NO) 2 (NH 3 ) 4 ](SO 4 )ÁH 2 O, the intradimer Pt II ÐPt II distance is 2.9749 (11) A Ê , which is clearly shorter than the value of 3.029 (2) A Ê reported for a different salt of the same cation, viz. [Pt II 2 (C 4 H 6 NO) 2 (NH 3 ) 4 ] 2 (PF 6 ) 3 -(NO 3 )Á

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Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.021 A Ê Some non-H atoms missing Disorder in solvent or counterion R factor = 0.060 wR factor = 0.121 Data-to-parameter ratio = 18.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/