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Preparation, metallation and alkylation of allenyl ethers

โœ Scribed by S. Hoff; L. Brandsma; J. F. Arens


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
430 KB
Volume
87
Category
Article
ISSN
0165-0513

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## Abstract For corrigendum see DOI:10.1002/anie.197507162

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A new method for the deprotection of prop-2-ynyl ethers lb-9b is described. Isomerisation of lb-9b to O-allenyl ethers ld-9d and deprotection by reaction with Hg(OCOCF3)2, aq.HCl, aq.CF3CO2H and best by use of a catalytic amount of OsO4 is described to obtain the alcohols la-9a in good yield. Appli