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Preparation of Aryl-Alkyl Ethers and Thioethers

✍ Scribed by Ian M. Downie; Dr. Harry Heaney; Graham Kemp

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
219 KB
Volume
14
Category
Article
ISSN
0044-8249

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✦ Synopsis

Abstract

For corrigendum see DOI:10.1002/anie.197507162

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Kinetic and equilibrium results are reported for the reactions of sulphite with the ethyl and phenyl ethers of 2,4,6-trinitrophenol and 2,4,6-trinitrothiophenol in 80/20 (v/v) water/DMSO. In each case 1:1 and 1:2 adducts are observed by reaction of sulphite at one or two unsubstituted ring positions