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Preparation, Crystal Structure, and Magnetic Properties of a New Dithiolene Ligand, 1,3,2-Dithiazole-4-thione-5-thiolate, and its Metal Complex

✍ Scribed by Nakamura, Tadamitsu; Sasamori, Kota; Kodama, Takeshi; Kikuchi, Koichi; Fujita, Wataru


Book ID
120156751
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
331 KB
Volume
8
Category
Article
ISSN
1861-4728

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Coordination geometries of bis(4-amino-3
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Bis bidentate complexes of 4-amino-3-trifluoromethyl-1,2,4-triazole-5-thione, SN 4 C 3 H 3 F 3 (afmt, 1) of the divalent ions Co and Ni, have been crystallized by direct combination of the ligand and metal nitrate hydrate salt in ethanol. The structures of the free ligand 1 as well as the complexes