Syntheses, Crystal Structures, and Optical Properties of Metal Complexes with 4′,5′-Diaza-9′-(4,5-disubstituted-1,3-dithiol-2-ylidene)fluorene Ligands
✍ Scribed by Qin-Yu Zhu; Wen Lu; Yong Zhang; Guo-Qing Bian; Jing Gu; Xiao-Min Lin; Jie Dai
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 539 KB
- Volume
- 2008
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The reactions of diorganotin dichloride [Ph~2~SnCl~2~, (PhCH~2~)~2~‐SnCl~2~ or (__n__‐Bu)~2~SnCl~2~] with potassium salt of 2, 5‐dimercapto‐4‐phenyl‐1, 3, 4‐thiodiazole gave complexes R~2~Sn (S~3~N~2~C~8~H~5~)~2~ (4: R = Ph; 5: R = PhCH~2~ and 6: R = __n__‐Bu), respectively. Characteriz
A novel bis (dmit) complex of copper (II), [(C 3 H 7 ) 4 N] 2 [Cu(dmit) 2 ] (1), where dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, was prepared and structurally characterized by X-ray single crystal diffraction. The copper (II) atom is tetracoordinated by four dmit S atoms, forming a nearly square