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Preparation and spectra of mercuribis (α-diazo ketones)

✍ Scribed by P. Yates; F.X. Garneau; J.P. Lokensgard

Book ID
103402125
Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
546 KB
Volume
31
Category
Article
ISSN
0040-4020

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Mercury derivatives of α-diazo ketones
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Oxidation of the monohydrazones of a-diketones with yellow mercuric oxide in the presence of base is a weil-known method for the preparation of a-diazo ketones (1). Some years ago, the interestinq observation was made (2) that when this reaction was applied to I, the hydrazone of an a-ketoaldehyde,

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The Wolff rearrangement of a-diazo ketones to prepare homologous acids or their derivatives has not been generally applied to the preparation of B-acetoxy acids. We have attempted to use this reaction to accomplish such a transformation but find that the major products are those resulting from g-eli