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The Wolff rearrangement of α-acetoxy diazo ketones

✍ Scribed by F.W. Bachelor; G.A. Miana

Book ID
104240858
Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
156 KB
Volume
8
Category
Article
ISSN
0040-4039

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✦ Synopsis

The Wolff rearrangement of a-diazo ketones to prepare homologous acids or their derivatives has not been generally applied to the preparation of B-acetoxy acids. We have attempted to use this reaction to accomplish such a transformation but find that the major products are those resulting from g-elimination from the rearranged acid or its derivatives.

📜 SIMILAR VOLUMES

Mercury derivatives of α-diazo ketones
Mercury derivatives of α-diazo ketones
✍ Peter Yates; François X. Garneau 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 170 KB

Oxidation of the monohydrazones of a-diketones with yellow mercuric oxide in the presence of base is a weil-known method for the preparation of a-diazo ketones (1). Some years ago, the interestinq observation was made (2) that when this reaction was applied to I, the hydrazone of an a-ketoaldehyde,