Communications- Preparation of α-Diazo Ketones
✍ Scribed by Morrison, Harry; Danishefsky, Samuel; Yates, Peter
- Book ID
- 120226742
- Publisher
- American Chemical Society
- Year
- 1961
- Tongue
- English
- Weight
- 182 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Oxidation of the monohydrazones of a-diketones with yellow mercuric oxide in the presence of base is a weil-known method for the preparation of a-diazo ketones (1). Some years ago, the interestinq observation was made (2) that when this reaction was applied to I, the hydrazone of an a-ketoaldehyde,
The rational synthesis of diazocyclopentadiene by the reaction of cyclopentadienyllithium with tosyl aside designed by Doering and De Puy(1) more than a decade ago has only recently been extended to the preparation of other diazo compounds (2,3,4,5). Regitz(&,j) has reported its application