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Preparation and Properties of Bis(trifluoromethylsulfuryl) Peroxide and Trifluoromethyl Trifluoromethanesulfonate

✍ Scribed by Noftle, Ronald E.; Cady, George H.

Book ID
121334980
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
411 KB
Volume
4
Category
Article
ISSN
0020-1669

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Infrared photochemistry of bis(trifluoro
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Bis(trifluoromethy1) peroxide is readily dissociated by multiple infrared photon excitation at COz laser wavelengths. The primary dissociation product is CF30; approximately 85% of the nascent radicals are further dissociated in the laser field to form CFzO and F. The F atoms then react with the rem