## Abstract A simple method for the determination of enantiomeric excess is described. It is based on depolarized Raman optical activity (ROA) measurements in rightβangle scattering employing the incident ciruclar polarization (ICP) modulation approach. The accuracy of this method was assessed util
β¦ LIBER β¦
Preparation and Enantiomeric Excess Determination of Optically Active BINOL and Derivatives
β Scribed by Brian E. Love
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 11 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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Oxazolidine derivatives of p-amino alcohols such as ephedrine have been resolved by -C NMR spedroscopy using Eu(hfc), as a chiral shift reagent. The method is quantitative in the determination of enantiomeric excess, and is advantageous where 'H NMR is of limited use owing, for example, to signitica