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Determination of enantiomeric excess by 13C NMR spectroscopy

✍ Scribed by V. N. Gogte; R. K. Nanda; A. A. Natu; V. S. Pandit; M. K. Sastry

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
283 KB
Volume
22
Category
Article
ISSN
0749-1581

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✦ Synopsis

Oxazolidine derivatives of p-amino alcohols such as ephedrine have been resolved by -C NMR spedroscopy using Eu(hfc), as a chiral shift reagent. The method is quantitative in the determination of enantiomeric excess, and is advantageous where 'H NMR is of limited use owing, for example, to signiticant line broadening.

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