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Chiral Reagents for the Determination of Enantiomeric Excess and Absolute Configuration Using NMR Spectroscopy

✍ Scribed by Thomas J. Wenzel; James D. Wilcox


Publisher
John Wiley and Sons
Year
2003
Weight
52 KB
Volume
34
Category
Article
ISSN
0931-7597

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The LIS values produced by Eu(fodJ3 for the CF3-19F NMR signals of the MlTA e s t e r s of different stereoisomeric secondary alcohols have been measured. The applicability o f these values for assigning the absolute configuration of the alcohols has been studied. The advantages of t h i s method ov