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Preparation and crystal structure of the cluster complex Os7H2(CO)21P(OMe)3

โœ Scribed by Gregory L. Powell; Thomas F. Tekut


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
323 KB
Volume
229
Category
Article
ISSN
0020-1693

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โœ Annaย M. Trzeciak; Beata Borak; Zbigniew Ciunik; Jรณzefย J. Ziรณล‚kowski; M.ย Fรกtimaย C ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 178 KB

## Abstract Rhodium complexes of formula [RhBp(CO)P] [Bp = bis(pyrazolylborate), P = P(NC~4~H~4~)~3~ 1, PPh~3~ 2, PCy~3~ 3, P(C~6~H~4~OMeโ€4)~3~ 4] have been prepared by exchange of the acetylacetonate (acac^โˆ’^) ligand in [Rh(acac)(CO)P] complexes. The spectroscopic and electrochemical properties as