Preliminary observations of the orientation dependence of H2-Ar scattering by a new technique
β Scribed by H. Moerkerken; M. Prior; J. Reuss
- Book ID
- 103328307
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 764 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0031-8914
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## Abstract The flash photolysis resonance fluorescence technique has been used to reinvestigate the kinetics of the oxygen atomβoxygen molecule combination reaction. Thirdβorder rate constants for O~2~, N~2~, and Ar as deactivant molecules were determined over the temperature range of 219β368 K. T
Ra?e constants for the reaction of 0(3P) atoms with CaH4, CaHB and NO(M = NpO) have been measured over the temperature range 300-392Β°K using a modulation-phase shifi technique. The Arrhenius expressions obtained are: C2H4, k2 = 3.37 X 10' exp[-(1270 -f 200)/RT] liter mole-' see-', CJH~, kz = 2.08 x