The electronic non-diagonal Born-Oppenheimer coupling matrix elements between the molecular h?drogen DIE, state and the B' L Zu end B 1Z; u states were calculated in the Hartree-Fock approx-imztion at R= 1.0,1.2,1.6 and 2.0 au. These were used to calculate the predissociation widths for the v = 3 to
Predissociation of the 3pπ D 1Πu+ state in H2, HD, and D2
✍ Scribed by P.M. Dehmer; W.A. Chupka
- Book ID
- 107732272
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 362 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0009-2614
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The predissociation of H2 molecules in the 3prr D ' KI", state has been studied by Farm-profile and~sis of the Rs have been measured. Stron, 0 indication of the opening of a new channel of dissociation is reported\\_ Coupling with the B"B t Z: state may be responsible for this.
The optogalvanic spectrum and the emission spectrum of the highly excited Hz and Dz in a dc discharge have been investigated. Five bands of the triplet systems for Hz and D2 were observed in the region of 16130 to 17440 cm-': between the c 'II, state and the h 'Xl, g 'C: , i 'iI,, and j '4 states an
The transition probabilities for hydrogen D 3pn lll,(v'= 2 to 17) +X1 Z~(IJ" = 0) bands have been measured using synchrotron radiation\_ Good agreement is obtained with published theoretic -9 calculations.