Predissociation and geminate recombination kinetics of I2 in liquid xenon and CCl4
β Scribed by D.F. Kelley; P.M. Rentzepis
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 358 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The kmcr~cs of I2 prcdlssoclallon and recombmauon hare been studled by pILosecond spcc~roscopy Pxullssocutlon occurs with :! llretlme of = 14 ps. and the gemmate recombmarIon process proceeds ~~11 --do ps hfctunc. The spectra mdlate the ew&xxc of a prcvlously undcrecrcd l-CC4 complex wth >150 ps hicumL
π SIMILAR VOLUMES
The resonance Raman overtone progressions of in following excitation in the bound and continuum parts of I 2 CCl 4 the B state are presented. It is shown that the Raman contribution from the bound part is damped by predissociation as that of an outgoing wavepacket crossing over to the purely repulsi
Excitation of the B 3tTu+u state of 12 in CC& solution with ~8 ps fwhm 531 nm mode-locked pulses yields substantial fluorescence, which contrasts with the pure resonance Raman emission spectrum displayed under 5 14.5 nm cw argon ion laser pumping.
The solubility of fluorotrichloromethane (CFCI3), trichloromethane (CHCI3), tetrachloromethane (CCI4) and trichloroethylene (C2HCI 3) in liquid nitrogen at 77.4 K has been investigated. A combination of filtration and gas chromatography methods was used. The experimental results were compared with t