Prediction of solubilities for tar extraction by supercritical carbon dioxide
โ Scribed by Keith D. Bartle; Anthony A. Clifford; Gavin F. Shilstone
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 486 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0896-8446
No coin nor oath required. For personal study only.
โฆ Synopsis
Predictions are given for the solubilities of four compounds (naphthalene, phenanthrene, phenol, and 2-naphthol) in carbon dioxide at six temperatures between 40 "C and 100 "C and pressures up to 240 bar. The data are intended to be relevant to the extraction of coal-gasification tars. The Peng-Robinson equation-of-state was used for predictions. Temperature-dependent interaction parameters were obtained using, where possible, the published solubility data.
๐ SIMILAR VOLUMES
frisches, 44-93. Tag oxidiertes Fett) waren dle Vitamin E-Gehalte hoher als in den Proben der Gruppe III (1.-43. Tag oxidiertes, 44.-93. Tag frisches Fett). Die Ergebnisse zeigen eindeutig, d d oxidierte Futterfette einen EinfluB auf den Vitamin E-Stoffwechsel ausiiben. Alle drei Futterungs- gruppen
Dioxins and dibenzofurans are suspected to be quite toxic. They are fat soluble, and therefore, accumulate in fat-rich tissues (e.g., fish liver) and in products like milk. They have been detected in a large amount of food raw materials. Therefore it is urgent to find ways to purify such materials.
A new experimental method has been developed for measuring the equilibrium solubility of heavy solutes in supercritical CO2. The micro-SFE (supercritical-fluid extraction) is coupled to supercriticalfluid chromatography (SFC), both operating under the same temperature, pressure, and CO2 flowrate. Na